Сrown- and Sulfophthalocyanines in Low-Molecular-Weight Hydrogels: Properties, Molecular State, and Release

N. F. Goldshleger,^a@1 A. S. Lobach,^a N. N. Dremova,^a M. A. Lapshina,^a A. M. Kolesnikova,^a V. E. Baulin,^b,c@2 and A. Yu. Tsivadze^b

^aInstitute of Problems of Chemical Physics RAS, 142432 Chernogolovka, Russia

^bA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 119071 Moscow, Russia

^cInstitute of Physiologically Active Compounds RAS, 142432 Chernogolovka, Russia

^@1Corresponding author E-mail: nfgold@icp.ac.ru

^@2Corresponding author E-mail: mager1988@gmail.com

DOI: 10.6060/mhc170830g

Macroheterocycles 2017 10(4-5) 531-539

In continuation of our previous studies, we explored the solubilization of crown- and sulfophthalocyanines in the presence of bile salts (BS), sodium deoxycholate, and sodium taurodeoxycholate. The formation of BS-based low-molecular-weight hydrogels was observed and their modification with 15-crown-5-phthalocyanines was studied. Some characteristics of hybrid gels and xerogels are presented, and the process of prolonged release of active component from gel under the action of external stimuli was studied in detail.

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Сrown- and Sulfophthalocyanines in Low-Molecular-Weight Hydrogels: Properties, Molecular State, and Release

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