Unusual Reactivity of Aliphatic and Aromatic Amines with Bromoalkyl Derivatives of Thiacalix[4]arene in 1,3-Alternate Stereoisomeric Form

Vladimir A. Burilov,^a@ Regina R. Ibragimova,^a Bulat H. Gafiatullin,^a Ramil I. Nugmanov,^a Svetlana E. Solovieva,^a,b and Igor S. Antipin^a,b

^aDepartment of Organic Chemistry, Kazan Federal University, 420008 Kazan, Russian Federation

^bA.E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Centre of Russian Academy of Sciences, 420088 Kazan, Russian Federation

^@Corresponding author E-mail: ultrav@bk.ru

DOI: 10.6060/mhc170514b

Macroheterocycles 2017 10(2) 215-220

For the first time a series of new cationic amphiphilic p-tert-butylthiacalix[4]arene derivatives adopting 1,3-alternate stereoisomeric form was synthesized by quaternization of several tertiary amines and N-heterocycles. The structure of all products was well-defined using modern physical technics. The influence of calixarene and amine sterical hindrances on reactivity is discussed.

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Unusual Reactivity of Aliphatic and Aromatic Amines with Bromoalkyl Derivatives of Thiacalix[4]arene in 1,3-Alternate Stereoisomeric Form

References: