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ISSN 1998-9539

Unusual Reactivity of Aliphatic and Aromatic Amines with Bromoalkyl Derivatives of Thiacalix[4]arene in 1,3-Alternate Stereoisomeric Form

Vladimir A. Burilov,a@ Regina R. Ibragimova,a Bulat H. Gafiatullin,a Ramil I. Nugmanov,a Svetlana E. Solovieva,a,b and Igor S. Antipina,b
aDepartment of Organic Chemistry, Kazan Federal University, 420008 Kazan, Russian Federation
bA.E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Centre of Russian Academy of Sciences, 420088 Kazan, Russian Federation
@Corresponding author E-mail: ultrav@bk.ru
 
DOI: 10.6060/mhc170514b
Macroheterocycles 2017 10(2) 215-220
 
For the first time a series of new cationic amphiphilic p-tert-butylthiacalix[4]arene derivatives adopting 1,3-alternate stereoisomeric form was synthesized by quaternization of several tertiary amines and N-heterocycles. The structure of all products was well-defined using modern physical technics. The influence of calixarene and amine sterical hindrances on reactivity is discussed.

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