Synthesis, Physicochemical Characterization and Pyridine Binding to (2,3,7,8,12,18-Hexamethyl-13,17-diethyl-5-(2-pyridyl)- porphinato)cobalt(II)

Ekaterina N. Ovchenkova,^a@ Nataliya G. Bichan,^a Alexander S. Semeikin,^b and Tatyana N. Lomova^a

Dedicated to Prof. Oleg A. Golubchikov on the occasion of his 70^th Birthday

^aG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russian Federation

^bIvanovo State University of Chemistry and Technology, Research Institute of Macroheterocyclic Compounds, 153000 Ivanovo, Russian Federation

^@Corresponding author E-mail: enk@isc-ras.ru

DOI: 10.6060/mhc170301o

Macroheterocycles 2018 11(1) 79-84

New (2,3,7,8,12,18-hexamethyl-13,17-diethyl-5-(2-pyridyl)porphinato)cobalt(II) (Co^IIP) was obtained in the reaction of 2,3,7,8,12,18-hexamethyl-13,17-diethyl-5-(2-pyridyl)porphyrin with Co(AcO)₂^.4H₂O in boiling DMF. This porphyrin complex was characterized by UV-Vis, IR, ¹H NMR and mass spectra. Coordination of pyridine to Co^IIP was studied by spectrophotometric titration. Cobalt(II) complex was found to react with pyridine forming 1:1 donor-acceptor complex in one-step reversible process. The obtained results are of interest for the creating of porphyrin-based donor-acceptor systems as components for photoactive materials.

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Synthesis, Physicochemical Characterization and Pyridine Binding to (2,3,7,8,12,18-Hexamethyl-13,17-diethyl-5-(2-pyridyl)- porphinato)cobalt(II)

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