Hybrid Materials of Zinc(II) Tetra-tert-butylphthalocyanine and Zinc(II) Tetra-tert-butylnaphthalocyanine with Single Walled Carbon Nanotubes: Structure and Sensing Properties

Maxim S. Polyakov^a@ and Tamara V. Basova^a,b

^aNikolaev Institute of Inorganic Chemistry, 630090 Novosibirsk, Russia

^bNovosibirsk State University, 630090 Novosibirsk, Russia

^@Corresponding author E-mail: maxpol@niic.nsc.ru

DOI: 10.6060/mhc161176p

Macroheterocycles 2017 10(1) 31-36

The influence of extension of the aromatic core of phthalocyanines derivatives on the properties of the functionalized single walled carbon nanotubes (CNT) is studied. For this purpose the comparative study of the structural features and sensing properties of the CNT functionalized with zinc 2,9,16,23-tetra-tert-butylphthalocyanine (ZnPc) and zinc 2,11,20,29-tetra-tert-butyl-2,3-naphthalocyanine complex (ZnNc) is carried out. The adsorption of ZnPc and ZnNc molecules onto the CNT surface has been confirmed by Raman spectroscopy, SEM, and thermogravimetric analysis. It was determined that the number of ZnNc molecules anchored on the CNT walls is more than the number of ZnPc molecules. The more preferable π-π interaction of ZnNc molecules with CNT appears to be due to the bigger number of π-electrons forming naphthalocyanine aromatic system. Thin films of pristine CNT, CNT/ZnPc and CNT/ZnNc hybrids were prepared by drop casting onto interdigitated electrodes and applied as active layers to detect ammonia vapour (10-50 ppm) by measuring electrical resistance changes. It has been shown that sensor response of the CNT/ZnNc hybrid toward ammonia vapours is lager than that of CNT/ZnPc hybrid.

References:

Click here to expand or collapse this section

1. Dini D., Hanack M. Physical Properties of Phthalocyanine-based Materials. In The Porphyrin Handbook. Phthalocyanines: Properties and Materials (Kadish K.M., K.M. Kevin, R. Smith Ed.) San Diego: Academic Press, 2003. p. 1-140.
https://doi.org/10.1016/B978-0-08-092391-8.50007-8

2. Hughes S., Spruce G., Wherrett B.S. and Kobayashi T. J. Appl. Phys. 1997, 81, 5905-5912.
https://doi.org/10.1063/1.364377

3. Kouzeki T., Tatezono S., Yanagi H. J. Phys. Chem. 1996, 100, 20097-20102.
https://doi.org/10.1021/jp962307j

4. Yanagi H., Kanbayashi Y., Schlettwein D., Woehrle D., Armstrong N.R. J. Phys. Chem. 1994, 98, 4760-4766.
https://doi.org/10.1021/j100068a045

5. Basova T.V., Hassan A., Krasnov P.O., Gürol I., Ahsen V. Sensors and Actuators B 2015, 216, 204-211.
https://doi.org/10.1016/j.snb.2015.04.032

6. Gao L.D., Qian X.H. J. Fluor. Chem. 2002, 113, 161-165.
https://doi.org/10.1016/S0022-1139(01)00539-5

7. Wang B., Wu Y., Wang X., Chen Z., He C. Sensors and Actuators B 2014, 190, 157-164.
https://doi.org/10.1016/j.snb.2013.08.066

8. Jiang D.P., Lu A.D., Li Y.J., Pang X.M., Hua Y.L. Thin Solid Films 1991, 199, 173-179.
https://doi.org/10.1016/0040-6090(91)90063-4

9. Chicharro M., Zapardiel A., Bermejo E. Anal. Bioanal. Chem. 2002, 373, 277-283.
https://doi.org/10.1007/s00216-002-1345-4

10. Fernandez-Sanchez J. F., Nezel T., Steiger R., Spichiger-Keller U. E. Sensors and Actuators B 2006, 113, 630-638.
https://doi.org/10.1016/j.snb.2005.07.012

11. Chakane S., Gokarna A., Bhoraskar S.V. Sensors and Actuators B 2003, 92, 1-5.
https://doi.org/10.1016/S0925-4005(03)00124-2

12. Zhao L., Zhu S., Zhou J. Sensors and Actuators B 2012, 171, 563-571.
https://doi.org/10.1016/j.snb.2012.05.035

13. Fernandez-Sanchez J. F., Fernandez I., Steiger R., Beer R., Cannas R., Spichiger-Keller U.E. Adv. Funct. Mater. 2007, 17, 1188-1198.
https://doi.org/10.1002/adfm.200600428

14. Viricelle J. P., Pauly A., Mazet L., Brunet J., Bouvet M., Varenne C., Pijolat C. Mater. Sci. Eng. C. 2006, 26, 186-195.
https://doi.org/10.1016/j.msec.2005.10.062

15. Uwira V., Schutze A., Kohl D. Sensors and Actuators B 1995, 26, 153-157.
https://doi.org/10.1016/0925-4005(94)01577-5

16. Jakubik W., Urbanczyk M., Maciak E. Sensors and Actuators B 2007, 127, 295-303.
https://doi.org/10.1016/j.snb.2007.07.026

17. Argote M.R., Guillen E.S., Porras A.G.G., Torres O.S., Richard C., Zagal J.H., Bedioui F., Granados S.G., Griveau S. Electroanal. 2014, 26, 507-512.
https://doi.org/10.1002/elan.201300578

18. Feng X., Irle S., Witek H., Morokuma K., Vidic R., Borguet E.J. J.Am. Chem. Soc. 2005, 127, 10533-10538.
https://doi.org/10.1021/ja042998u

19. Lucci M., Reale A., Carlo D.A., Orlanducci S., Tamburri E., Terranova M.L., Davolic I., Di Natale C., D'Amicoa A., Paolesse R. Sensors and Actuators B 2006, 118, 226-231.
https://doi.org/10.1016/j.snb.2006.04.027

20. Alwarappan S., Liu G., Li C. Z. Nanomedicine: Nanotechnol., Biology Medicine 2010, 6, 52-57.
http://dx.doi.org/10.1016/j.nano.2009.06.003

21. Jyothirmayee Aravind S. S. and Ramaprabhu S. Sensors and Actuators B 2011, 155, 679-686.
https://doi.org/10.1016/j.snb.2011.01.029

22. Wang X., Liu Y., Qiu W., Zhu D. J. Mater. Chem. 2002, 12, 1636-1639.
https://doi.org/10.1039/b201447e

23. Bogani L., Danieli C., Biavardi E., Bendiab N., Barra A.L., Dalcanale E., Wernsdorfer W., Cornia A. Angew. Chem. Int. Ed. 2009, 48, 746-750.
https://doi.org/10.1002/anie.200804967

24. Bartelmess J., Ballesteros B., De la Torre G., Kiessling D., Campidelli S., Prato M., Torres T., Guldi D.M. J. Am. Chem. Soc. 2010, 132, 16202-16211.
https://doi.org/10.1021/ja107131r

25. Ogbodu R.O., Antunes E., Nyokong T. Dalton Trans. 2013, 42, 10769-10777.
https://doi.org/10.1039/c3dt50335f

26. Kaya E.N., Tuncel S., Basova T.V., Banimuslem H., Hassan A., Gürek A.G., Ahsen V., Durmuş M. Sensors and Actuators B 2014, 199, 277-283.
https://doi.org/10.1016/j.snb.2014.03.101

27. Zhang X., Feng Y., Tang S., Feng W. Carbon 2010, 48, 211-216.
https://doi.org/10.1016/j.carbon.2009.09.007

28. Feng Y., Zhang X., Feng W. Organic Electronics 2010, 11, 1016-1019.
https://doi.org/10.1016/j.orgel.2010.02.016

29. Feng W., Li Y., Feng Y., Wu J. Nanotechnology 2006, 17, 3274-3279.
https://doi.org/10.1088/0957-4484/17/13/033

30. Lebadeva N.Sh., Pavlycheva N.A., Parfenuk E.V., Vyugin A.I. J. Chem. Thermodynamics 2006, 38(2), 165-172.
https://doi.org/10.1016/j.jct.2005.04.001

31. Janczak J., Kubiak R. Polyhedron 2001, 20(24-25), 2901-2909.
https://doi.org/10.1016/S0277-5387(01)00829-4

32. Ceyhan T., Altindal A., Özkaya A.R., Çelikbiçak Ö., Salih B., Kemal Erbil M., Bekaroğlu Ö. Polyhedron 2007, 26, 4239-4249.
https://doi.org/10.1016/j.poly.2007.05.028

33. Durmus M., Nyokong T. Polyhedron 2007, 26, 2767-2776.
https://doi.org/10.1016/j.poly.2007.01.018

34. Karousis N., Ortiz J., Ohkubo K., Hasobe T., Fukuzumi S., Sastre-Santos A., Tagmatarchis N. J. Phys. Chem. C. 2012, 116, 20564-20573.
https://doi.org/10.1021/jp305783v

35. Wepasnick K.A., Smith B.A., Bitter J.L. Anal. Bioanal. Chem. 2010, 396, 1003-1014.
https://doi.org/10.1007/s00216-009-3332-5

36. Mugadza T., Nyokong T. Electrochim. Acta 2010, 55, 6049-6057.
https://doi.org/10.1016/j.electacta.2010.05.065

37. Ballesteros B., De la Torre G., Ehli C., Rahman G.M.A., Rueda F., Guidi D.M., Torres T. J. Am. Chem. Soc. 2007, 129, 5061-5068.
https://doi.org/10.1021/ja068240n

38. Casiraghi C., Hartschuh A., Qian H., Pliscanec S., Georgia C., Fasoli A., Novoselov K.S., Basko D.M., Ferrari A.C. Nano Lett. 2009, 9, 1433-1441.
https://doi.org/10.1021/nl8032697

39. Dyke C., Tour J. Nano Lett. 2003, 3, 1215-1218.
https://doi.org/10.1021/nl034537x

40. Alvarez L., De la Fuente G., Righi A., Rols S., Anglaret E., Sauvajol J., Munoz E., Maser W., Benito A., Martinez M. Phys. Rev. B. 2001, 63, 153401.
https://doi.org/10.1103/PhysRevB.63.153401

41. Huo D., Yang L., Hou C., Fa H., Luo X., Lu Y., Zheng X., Yang J., Yang L. Spectrochimica Acta A 2009, 74, 336-343.
https://doi.org/10.1016/j.saa.2009.06.009

42. Gotovac S., Honda H., Hattori Y., Takahashi K., Kanoh H., Kaneko K. Nano Lett. 2007, 7, 583-587.
https://doi.org/10.1021/nl0622597

43. Zhang Y., Zhang J., Son H., Kong J., Liu Z. J. Am. Chem. Soc. 2005, 127, 17156-17157.
https://doi.org/10.1021/ja056793c

44. Wang B., Zhou X., Wu Y., Chen Z., He C., Zuo X. Sensors and Actuators B 2012, 161, 498-503.
https://doi.org/10.1016/j.snb.2011.10.067

45. Chidawanyika W., Nyokong T. Carbon 2010, 48, 2831-2838.
https://doi.org/10.1016/j.carbon.2010.04.015

Attachment	Size
mhc161176p.pdf	1.71 MB

Журнал "Макрогетероциклы"

Navigation

Languages

News

Search

Hybrid Materials of Zinc(II) Tetra-tert-butylphthalocyanine and Zinc(II) Tetra-tert-butylnaphthalocyanine with Single Walled Carbon Nanotubes: Structure and Sensing Properties

References: