Pd(0)-Сatalyzed Amination in the Synthesis of Planar-Chiral Macrobicyclic Compounds Comprising 1,5-Disubstituted Anthraquinone Moiety

Olga K. Grigorova, Alexei D. Averin,^@ Olga A. Maloshitskaya, Victor B. Rybakov, and Irina P. Beletskaya

Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Russia

^@Corresponding author E-mail: alexaveron@yandex.ru

DOI: 10.6060/mhc161069a

Macroheterocycles 2016 9(4) 418-424

Planar-chiral N- and O-containing macrocycles were obtained via enantioselective Pd(0)-catalyzed amination of 1,5-dichloroanthraquinone and converted into corresponding di(bromobenzyl) substituted derivatives. The latter compounds were introduced in the Pd(0)-catalyzed macrocyclization reactions with several linear oxadiamines and certain pairs of reagents gave macrobicyclic compounds with a central planar-chiral structural fragment.

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Pd(0)-Сatalyzed Amination in the Synthesis of Planar-Chiral Macrobicyclic Compounds Comprising 1,5-Disubstituted Anthraquinone Moiety

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