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ISSN 1998-9539

Functionalisation of Macroheterocycles with Preserving and Changing Their Sizes

G. Yu. Ishmuratov,@ M. P. Yakovleva, V. A. Vydrina, М. А. Shutova, N. M. Ishmuratova,  and A. G. Tolstikov
Ufa Institute of Chemistry, Russian Academy of Sciences, 450054 Ufa, Russian Federation
@Corresponding author E-mail:
DOI: 10.6060/mhc161066i
Macroheterocycles 2017 10(3) 345-379
This review presents methods for functionalisation of macroheterocycles occurring both with preservation and alteration of their core. It is shown that the most common methods do not affect the main ring. While functionalisation of macroheterocycles accompanied by both a decrease and an increase of their size is less common, the examples given in the literature indicate the prospects of macroheterocycle functionalisation by described methods in direct synthesis of substances for different purposes: pharmacologically active compounds, selective ligands for various (mainly transient and rare-earth) metals, odorants, etc.


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