Homotrinuclear Сomplexes of [30]Trithiadodecaazahexaphyrine with Transition Metals: Ni(II), Cu(II) and Mn(II)

Evgeny N. Ivanov,^a Olga N. Trukhina,^b Oskar I. Koifman,^a Mikhail K. Islyaikin^a@

Dedicated to Professor Tomas Torres Cebada on the occasion of his 65th birthday

^aInternational Research Laboratory on Nanomaterials, Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russian Federation

^bDepart. de Química Orgánica (C-I), Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain

^@Corresponding author E-mail: islyaikin@isuct.ru

DOI: 10.6060/mhc160965i

Macroheterocycles 2016 9(3) 225-229

Homotrinuclear complexes were synthesized by reaction of [30]trithiadodecaazahexaphyrine (hemihexaphyrazine) with nickel(II), copper(II) or manganese(II) acetates in phenol. The compounds were characterized by UV-Vis, IR spectroscopy, mass-spectrometry and elemental analysis. Study of thermal behavior of manganese complex has shown high thermal stability. The structure of a cationic copper complex observed in mass-spectrum was elucidated by quantum chemistry calculations at the DFT level.

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Homotrinuclear Сomplexes of [30]Trithiadodecaazahexaphyrine with Transition Metals: Ni(II), Cu(II) and Mn(II)

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