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ISSN 1998-9539

Cu(II) Сrown-Tetraphenylporphyrinate: Molecular Structure and Evaluation of the Formation of Multinuclear Complexes with s-Metals

Vasily E. Kotsuba,a@ Nadezhda N. Kolyadina,a Yan V. Zubavichus,b Pavel V. Dorovatovskii,b and Victor N. Khrustaleva,c


Dedicated to our colleague, teacher and friend – professor A. T. Soldatenkov (December 1938 – October 2016), who has unexpectedly left us


aRUDN University, Moscow 117198, Russian Federation

bNational Research Center “Kurchatov Institute”, Moscow 123182, Russian Federation

cA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russian Federation

@Corresponding author E-mail:


DOI: 10.6060/mhc160960k

Macroheterocycles 2016 9(3) 234-237


A novel neutral complex of a crown-fused tetraphenylporphyrin was obtained and its structure determined by X-ray analysis. Quantum chemical calculations were performed to establish the possibility of exploiting its crown units for the formation of multinuclear complexes with cations of alkaline and alkaline earth metals.


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