Factors Affecting the Structural Organization of Hemicyanine Chromoionophores in Langmuir Monolayers

Alexander V. Shokurov, Daria A. Silant’yeva, Vladimir V. Arslanov, and Sofiya L. Selektor^@

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences, 119071 Moscow, Russia

^@Corresponding author E-mail: pcss_lab@mail.ru

DOI: 10.6060/mhc160855s

Macroheterocycles 2016 9(4) 395-401

The present work deals with processes of structure-formation and aggregation behavior of hemicyanine chromoionophores in Langmuir monolayers and Langmuir-Blodgett films. It is revealed that the appearance of excimers upon compression of monolayers of these compounds is associated with cation-ionophore group interaction. The key role of the organic solvent in the preorganization of such monolayers on subphases containing indifferent cations is demonstrated. The extreme character of the dependence of the excimer formation efficiency on concentration of the above ions is shown, and optimum concentrations are identified.

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Factors Affecting the Structural Organization of Hemicyanine Chromoionophores in Langmuir Monolayers

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