Template Synthesis of Lanthanides Complexes with 5,15-Diphenyltetrabenzoporphyrin

Anatoly A. Rasputin, Andrey I. Koptyaev, Nikolay E. Galanin,^@ and Gennady P. Shaposhnikov

Ivanovo State University of Chemistry and Technology, Research Institute of Macroheterocyclic Сompounds, 153000 Ivanovo, Russia

^@Corresponding author E-mail: nik-galanin@yandex.ru

DOI: 10.6060/mhc160749g

Macroheterocycles 2017 10(3) 328-333

Method of template synthesis of lanthanides complexes with 5,15-diphenyltetrabenzoporphyrin was developed. It allows to obtain complexes with yield from 7 to 12 %, which is three times higher than in the known method. The structure of the complexes was established on the data of mass spectrometry (MALDI-TOF), ¹H NMR, IR and UV-Vis spectroscopy. It was determined that the yields of the compounds and their spectral characteristics depend on the ionic radius of the metals.

References:

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1. Shea P.B., Kanicki J., Cao Y., Ono N. Appl. Phys. Lett. 2005, 87, 173506–173506-3.
https://doi.org/10.1063/1.2115077

2. Shea P.B., Kanicki J., Ono N. J. Appl. Phys. 2005, 98, 014503–014503-7.
https://doi.org/10.1063/1.1949713

3. Shea P.B., Kanicki J., Pattison L.R., Petroff P., Kawano M., Yamada H., Ono N. J. Appl. Phys. 2006, 100, 034502–034502-7.
https://doi.org/10.1063/1.2220641

4. Shea P.B., Pattison L.R., Kawano M., Chen C., Chen J., Petroff P., Martin D.C., Yamada H., Ono N., Kanicki J. Synth. Met. 2007, 157, 190–197.
https://doi.org/10.1016/j.synthmet.2007.01.013

5. Shea P.B., Chen C., Kanicki J., Pattison L.R., Petroff P., Yamada H., Ono N. Appl. Phys. Lett. 2007, 90, 233107–233107-3.
https://doi.org/10.1063/1.2745227

6. Drobizhev M., Karotki A., Kruk M., Rebane A. Chem. Phys. Lett. 2002, 355, 175–182.
https://doi.org/10.1016/S0009-2614(02)00206-3

7. Vinogradov S.A., Lo L.W., Jenkins W.T., Evans S.M., Koch C., Wilson D.F. Biophys. J. 1996, 70, 1609–1617.
https://doi.org/10.1016/S0006-3495(96)79764-3

8. Vinogradov S.A., Wilson D.F. J. Chem. Soc. Perkin Trans. 2. 1995, 103–111.
https://doi.org/10.1039/p29950000103

9. Tikhomirova K.V., Chumakov D.E., Khoroshutin A.V., Anisimov A.V. Macroheterocycles 2012, 5, 59–66.
https://doi.org/10.6060/mhc2012.111047k

10. Galanin N.E., Shaposhnikov G.P., Koifman O.I. Russ. Chem. Rev. 2013, 82, 412–428.
https://doi.org/10.1070/RC2013v082n05ABEH004317

11. Galanin N.E., Yakubov L.A., Shaposhnikov G.P., Bykova V.V., Anan'eva G.A. Liq. Cryst. and their Appl. 2010, 2, 25–31 (in Russ).

12. Galanin N.E., Yakubov L.A., Shaposhnikov G.P., Pakhomov G.L. Russ. J. Org. Chem. 2011, 47, 771–777.
https://doi.org/10.1134/S1070428011050186

13. Galanin N.E. Diss. doc. chem. sci. Ivanovo: ISUCT, 2010. 300 p.

14. Kudrik E.V., Islyaikin M.K., Frantseva S.V. Zh. Obshch. Khim. 1997, 67, 1202–1205 (in Russ).

15. Lee M.R., Liou S.T., Cheng R.J. J. Am. Soc. Mass. Spectrom. 1997, 8, 62–67.
https://doi.org/10.1016/S1044-0305(96)00137-7

16. Filatov M.A., Lebedev A.Y., Vinogradov S.A., Cheprakov A.V. J. Org. Chem. 2008, 73, 4175–4185.
https://doi.org/10.1021/jo800509k

17. Filatov M.A., Cheprakov A.V., Beletskaya I.P. Eur. J. Org. Chem. 2007, 3468–3475.
https://doi.org/10.1002/ejoc.200700014

18. Mamardashvili N.Zh., Golubchikov O.A. Uspekhi Khimii 2001, 70, 656–686.
https://doi.org/10.1070/RC2001v070n07ABEH000661

19. Berezin B.D. Coordination Compounds of Porphyrins and Phthalocyanines. New York: Wiley, 1981. 286 p.

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Template Synthesis of Lanthanides Complexes with 5,15-Diphenyltetrabenzoporphyrin

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