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ISSN 1998-9539

Template Synthesis of Lanthanides Complexes with 5,15-Diphenyltetrabenzoporphyrin

Anatoly A. Rasputin, Andrey I. Koptyaev, Nikolay E. Galanin,@ and Gennady P. Shaposhnikov
Ivanovo State University of Chemistry and Technology, Research Institute of Macroheterocyclic Сompounds, 153000 Ivanovo, Russia
@Corresponding author E-mail:
DOI: 10.6060/mhc160749g
Macroheterocycles 2017 10(3) 328-333
Method of template synthesis of lanthanides complexes with 5,15-diphenyltetrabenzoporphyrin was developed. It allows to obtain complexes with yield from 7 to 12 %, which is three times higher than in the known method. The structure of the complexes was established on the data of mass spectrometry (MALDI-TOF), 1H NMR, IR and UV-Vis spectroscopy. It was determined that the yields of the compounds and their spectral characteristics depend on the ionic radius of the metals.


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