Effect of pH on Acid-Base and Photophysicochemical Properties of 2,3,9,10,16,17,23,24-Octacarboxyphthalocyanines in Aqueous Media

Oleg L. Kaliya,^a,b Nina A. Kuznetsova,^b@ Roman A. Bulgakov,^b Ludmila I. Solovyova,^b Ekaterina N. Shevchenko,^b Ludmila K. Slivka,^b and Evgeny A. Lukyanets^b

^aMoscow Technological University, Institute of Fine Chemical Technology, 119571 Moscow, Russia

^bOrganic Intermediates and Dyes Institute, 123001 Moscow, Russia

^@Corresponding author E-mail: lab32@niopik.ru

DOI: 10.6060/mhc160646k

Macroheterocycles 2016 9(2) 186-192

The results of study of pH effect on the aggregation, acid-base and photophysicochemical properties of 2,3,9,10,16,17,23,24-octacarboxy substituted Zn, Al, Co, Pt and Pd phthalocyanines (MPc^oc) in aqueous media are presented. The ionization of peripheral carboxyl groups and axial ligation of central metal atom are the principal factors, governing aggregation. The multi-step ionization of MPc^ocs, induced by change of pH, was considered as pseudo two-step process affecting four carboxyl groups on each step. The photophysicochemical properties of three differently ionized forms of ZnPc^oc (unionized, tetra- and octacarboxylated) were studied..

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Effect of pH on Acid-Base and Photophysicochemical Properties of 2,3,9,10,16,17,23,24-Octacarboxyphthalocyanines in Aqueous Media

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