Tetraphenyltetrabenzoporphyrinates of Ni(II), Pd(II), Pt(II) and Pt(IV)

Olga V. Maltceva, Natalya V. Chizhova,^@ Roman S. Kumeev and Nugzar Zh. Mamardashvili

G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russia

^@Corresponding author E-mail: nvc@isc-ras.ru

DOI: 10.6060/mhc160541c

Macroheterocycles 2017 10(1) 68-71

The metal exchange reaction of5,10,15,20-tetraphenyltetrabenzoporphyrinate of Cd(II) withNi(II), Pd(II) and Pt(II) chlorides in DMF and phenol was investigated. Corresponding porphyrinates of Ni(II), Pd(II) and Pt(II) were obtained. 5,10,15,20-Tetraphenyltetrabenzoporphyrinate Pt(IV)(Br)₂was synthesized through direct addition of Br₂ to the porphyrinate Pt(II) in chloroform. The prepared compounds were identified by the methods of electronic absorption, ¹H NMR spectroscopy, mass spectrometry and elemental analysis.

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