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ISSN 1998-9539

Tetraphenyltetrabenzoporphyrinates of Ni(II), Pd(II), Pt(II) and Pt(IV)

Olga V. Maltceva, Natalya V. Chizhova,@ Roman S. Kumeev and Nugzar Zh. Mamardashvili

G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russia

@Corresponding author E-mail:


DOI: 10.6060/mhc160541c

Macroheterocycles 2017 10(1) 68-71


The metal exchange reaction of5,10,15,20-tetraphenyltetrabenzoporphyrinate of Cd(II) withNi(II), Pd(II) and Pt(II) chlorides in DMF and phenol was investigated. Corresponding porphyrinates of Ni(II), Pd(II) and Pt(II) were obtained. 5,10,15,20-Tetraphenyltetrabenzoporphyrinate Pt(IV)(Br)2was synthesized through direct addition of Br2 to the porphyrinate Pt(II) in chloroform. The prepared compounds were identified by the methods of electronic absorption, 1H NMR spectroscopy, mass spectrometry and elemental analysis.


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