Журнал "Макрогетероциклы"

Aleksey B. Burdukov,^a@ Rastislav Šipoš,^b Natalie V. Pervukhina,^a Nataliya V. Kuratieva,^a Ilia V. Eltsov,^c Mikhail A. Vershinin,^a Evgenii G. Boguslavsky,^a Danila B. Kal’nyi,^a,c Sofia L. Selektor,^d Alexander V. Shokurov,^d Yan Z. Voloshin,^e and Andrei A. Nefedov^c,f

^aNikolaev Institute of Inorganic Сhemistry SB RAS, 630090 Novosibirsk, Russia

^bSlovak University of Technology, 81237 Bratislava, Slovakia

^cNovosibirsk State University, 630090 Novosibirsk, Russia

^dFrumkin Institute of Physical Сhemistry and Electrochemistry RAS, 199071 Moscow, Russia

^eNesmeyanov Institute of Organoelement Compounds RAS, 119991 Moscow, Russia

^fVorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, 630090 Novosibirsk, Russia

^@Corresponding author E-mail: lscc@niic.nsc.ru

DOI: 10.6060/mhc160537b
Macroheterocycles 2016 9(3) 257-262

A boron-capped tris-dioximate iron(II) bis-macrocyclic clathrochelate with annulated dimethylquinoxaline heterocycle has been synthesized. The compound has been characterized with single-crystal X-ray diffraction, multinuclear NMR, IR, UV-vis spectrometry, CV and spectroelectrochemistry. The clathrochelate is capable of ligand-centered two-electron reversible reduction coupled with electrochromism (in solution and thin film).

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