Heterocyclic Subphthalocyanine Analogue – Boron(III) Subporphyrazine with Fused 1,2,5-Thiadiazole Rings

Mahmoud Hamdoush,^a Svetlana S. Ivanova,^a Georgy L. Pakhomov,^b and Pavel A. Stuzhin^a@

Dedicated to Professor Tomas Torres on the occasion of his 65th Birthday

^aResearch Institute of Macroheterocycles, Ivanovo State University of Chemical Technology, 153000 Ivanovo, Russia

^bInstitute for Physics of Microstructures, Russian Academy of Sciences, 603950 Nizhny Novgorod, Russia

^@Corresponding author E-mail: stuzhin@isuct.ru

DOI: 10.6060/mhc160424s

Macroheterocycles 2016 9(3) 230-233

Novel subphthalocyanine analogue – tris(1,2,5-thiadiazolo)subporphyrazinatoboron(III) chloride was prepared by interaction of 1,2,5-thiadiazolo-3,4-dicarbonitrile with BCl3 in chlorobenzene. Strong p-electron deficient nature of the fused 1,2,5-thiadiazole rings leads to hypsochromic shift of the Q-band to 538 nm.

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Heterocyclic Subphthalocyanine Analogue – Boron(III) Subporphyrazine with Fused 1,2,5-Thiadiazole Rings

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