Formation and Study of Nanostructured M-Monolayers and LS-Films of Triphenylcorrole

Thao T. Vu,^а Larissa A. Maiorova,^а@ Dmitrii B. Berezin,^а and Oskar I. Koifman^а,b

^aResearch Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russian Federation

^bG.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russian Federation

^@Corresponding author E-mail: valkovala@mail.ru

DOI: 10.6060/mhc151205m

Macroheterocycles 2016 9(1) 73-79

An experimental and theoretical study of 5,10,15-triphenylcorrole (H₃[(ms-Ph)₃Cor]) nano-structured floating layers (M-layers) was performed. The existence areas and characteristics of the structure and properties of stable monomolecular layers were determined. Main dependencies of the M-monolayer on the initial surface coverage degree were identified – the sizes of the nanoaggregate, aggregation number, surface area per molecule in a nanoaggregate, etc. A quantitative model of a monolayer with water and dry M-nanoaggregates was constructed. H₃[(ms-Ph)₃Cor] thin films on solid substrates were obtained using the Langmuir-Schaefer (LS) technique, and their spectral characteristics were explored.

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Formation and Study of Nanostructured M-Monolayers and LS-Films of Triphenylcorrole

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