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ISSN 1998-9539

Formation and Study of Nanostructured M-Monolayers and LS-Films of Triphenylcorrole

Thao T. Vu,а Larissa A. Maiorova,а@ Dmitrii B. Berezin,а and Oskar I. Koifmanа,b

aResearch Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russian Federation

bG.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russian Federation

@Corresponding author E-mail:


DOI: 10.6060/mhc151205m

Macroheterocycles 2016 9(1) 73-79


An experimental and theoretical study of 5,10,15-triphenylcorrole (H3[(ms-Ph)3Cor]) nano-structured floating layers (M-layers) was performed. The existence areas and characteristics of the structure and properties of stable monomolecular layers were determined. Main dependencies of the M-monolayer on the initial surface coverage degree were identified – the sizes of the nanoaggregate, aggregation number, surface area per molecule in a nanoaggregate, etc. A quantitative model of a monolayer with water and dry M-nanoaggregates was constructed. H3[(ms-Ph)3Cor] thin films on solid substrates were obtained using the Langmuir-Schaefer (LS) technique, and their spectral characteristics were explored.



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