Electrochemical Studies of Tetraheteroarenoporphyrazines in an Alkaline Solution

Dmitrii A. Filimonov, Svetlana V. Alekseeva, Michael I. Bazanov,^@ Oscar I. Koifman, and Michael S. Kokorin

Dedicated to the great worker in the macroheterocyclic area Oleg A. Golubchikov

Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

^@Corresponding author E-mail: bazanov@isuct.ru

DOI: 10.6060/mhc151204b

Macroheterocycles 2018 11(1) 52-58

The studies of electrochemical and electrocatalyticproperties of tetraheteroarenoporphyrazines in an alkaline solution are summarized in this work. The research of some macroheterocyclic compounds was carried out by method of cyclic voltammetry. The values of redoxpotentials related with the process of transformation of the central metal ionand organicligand were obtained. The effective number of electrons was calculated. The evaluation of electrocatalyticactivity of the compoundsin the reduction reactionof molecular oxygenin alkaline solution was carried out.

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Electrochemical Studies of Tetraheteroarenoporphyrazines in an Alkaline Solution

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