The Role of Oxygen in Electrochemical Reduction of Double-Decker Phthalocyaninates of Lanthanides

S. L. Selektor,^a@ A. V. Shokurov,^a A. A. Revina,^a V. V. Arslanov,^a Yu. G. Gorbunova,^a,b and A. Yu. Tsivadze^a,b

Dedicated to Prof. Mir Wais Hosseini, who has made a significant contributionto macroheterocycles chemistry, on the occasion of his anniversary

^aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 119071 Moscow, Russia

^bN.S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991 Moscow, Russia

^@Corresponding author E-mail: sofs@list.ru

DOI: 10.6060/mhc150765s

Macroheterocycles 2015 8(2) 135-142

The influence of air oxygen on the processes of electrochemical reduction of double-decker 15-crown-5 substituted lanthanide phthalocyaninates in solutions and Langmuir-Blodgett films on electrode surfaces was revealed. The multi-stage nature of the process, associated with formation of the intermediate oxygen-containing complexes of the studied compounds in the presence of atmospheric oxygen, was confirmed by cyclic voltammetry and spectroelectrochemical measurements. It was shown that spectra of the electrochemically reduced forms of complexes coincide with ones obtained via chemical reduction only upon application of extremely negative potentials or in the absence of air oxygen in electrolyte.

References:

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1. Tsivadze A.Y. Russ. Chem. Rev. 2004, 73, 5–23.

http://dx.doi.org/10.1070/RC2004v073n01ABEH000862

2. Kobayashi N. Coord. Chem. Rev. 2002, 227, 129–152.

http://dx.doi.org/10.1016/S0010-8545(02)00010-3

3. Nyokong T. Electronic Spectral and Electrochemical Behavior of Near Infrared Absorbing Metallophthalocyanines. In: Funct. Phthalocyanine Mol. Mater. (Jiang J., Ed.), Berlin: Springer Berlin Heidelberg, 2010, 135, 45–86.

http://dx.doi.org/10.1007/978-3-642-04752-7_2

4. Wöhrle D., Schnurpfeil G., Makarov S.G., Kazarin A., Suvorova O.N. Macroheterocycles 2012, 5, 191–202.

http://dx.doi.org/10.6060/mhc2012.120990w

5. Ng D.K.P., Jiang J. Chem. Soc. Rev. 1997, 26, 433–442.

http://dx.doi.org/10.1039/cs9972600433

6. Pushkarev V.E., Tomilova L.G., Tomilov Y.V. Russ. Chem. Rev. 2008, 77, 875–907.

http://dx.doi.org/10.1070/RC2008v077n10ABEH003879

7. Jiang J., Ng D.K.P. Acc. Chem. Res. 2009, 42, 79–88.

http://dx.doi.org/10.1021/ar800097s

8. Gorbunova Y.G., Lapkina L.A., Martynov A.G., Biryukova I.V., Tsivadze A.Y. Russ. J. Coord. Chem. 2004, 30, 245–251.

http://dx.doi.org/10.1023/B:RUCO.0000022799.63314.fc

9. Basova T., Jushina I., Gürek A.G., Ahsen V., Ray A.K. J. R. Soc. Interface 2008, 5, 801–806.

http://dx.doi.org/10.1098/rsif.2007.1241

10. Rodriguez-Mendez M.L., Aroca R., de Saja J.A. Chem. Mater. 1993, 5, 933–937.

http://dx.doi.org/10.1021/cm00031a010

11. Rodriguez-Mendez M.L., de Saja J.A. J. Porphyrins Phthalocyanines 2009, 13, 606–615.

http://dx.doi.org/10.1142/S1088424609000814

12. de Saja J.A., Rodríguez-Méndez M.L. Adv. Colloid Interface Sci. 2005, 116, 1–11.

http://dx.doi.org/10.1016/j.cis.2005.03.004

13. Besbes S., Plichon V., Simon J., Vaxiviere J. J. Electroanal. Chem. Interfacial Electrochem. 1987, 237, 61–68.

http://dx.doi.org/10.1016/0022-0728(87)80307-8

14. Li J., Gryko D., Dabke R.B., Diers J.R., Bocian D.F., Kuhr W.G., Lindsey J.S. J. Org. Chem. 2000, 65, 7379–7390.

http://dx.doi.org/10.1021/jo000490d

15. Gryko D., Li J., Diers J.R., Roth K.M., Bocian D.F., Kuhr W.G., Lindsey J.S. J. Mater. Chem. 2001, 11, 1162–1180.

http://dx.doi.org/10.1039/b008224o

16. Selektor S.L., Sheinina L.S., Shokurov A. V., Raitman O.A., Arslanov V. V., Lapkina L.A., Gorbunova Y.G., Tsivadze A.Y. Prot. Met. Phys. Chem. Surfaces 2011, 47, 447–456.

http://dx.doi.org/10.1134/S2070205111040162

17. Selektor S.L., Shokurov A. V. Prot. Met. Phys. Chem. Surfaces 2015, 51, 171–203.

http://dx.doi.org/10.1134/S2070205115020161

18. Gorbunova Y.G., Martynov A.G., Tsivadze A.Y. Crown Substituted Phthalocyanines: from Synthesis towards Materials In: Handbook of Porphyrin Science, Vol. 24 (Kadish K., Smith K., Guilard R., Eds.), Singapore: World Scientific Publishing, 2012, 271–388.

http://dx.doi.org/10.1142/9789814397605_0015

19. Bian Y., Jiang J., Tao Y., Choi M.T.M., Li R., Ng A.C.H., Zhu P., Pan N., Sun X., Arnold D.P., Zhou Z.-Y., Li H.-W., Mak T.C.W., Ng D.K.P. J. Am. Chem. Soc. 2003, 125, 12257–12267.

http://dx.doi.org/10.1021/ja036017+

20. Nekelson F., Monobe H., Shimizu Y. Chem. Commun. 2006, 37, 3874–3876.

http://dx.doi.org/10.1039/b607851f

21. Selektor S.L., Shokurov A. V., Raitman O.A., Sheinina L.S., Arslanov V.V., Birin K.P., Gorbunova Y.G., Tsivadze A.Y. Colloid J. 2012, 74, 334–345.

http://dx.doi.org/10.1134/S1061933X12020111

22. Selektor S.L., Shokurov A.V., Arslanov V.V., Gorbunova Y.G., Birin K.P., Raitman O.A., Morote F., Cohen-Bouhacina T., Grauby-Heywang C., Tsivadze A.Y. J. Phys. Chem. C 2014, 118, 4250–4258.

http://dx.doi.org/10.1021/jp411936k

23. Selector S.L., Shokurov A.V., Arslanov V.V., Gorbunova Y.G., Raitman O.A., Isakova A.A., Birin K.P., Tsivadze A.Y. Russ. J. Electrochem. 2012, 48, 218–233.

http://dx.doi.org/10.1134/S1023193512020164

24. Selector S.L., Arslanov V.V., Gorbunova Y.G., Raitman O.A., Sheinina L.S., Birin K.P., Tsivadze A.Y. J. Porphyrins Phthalocyanines 2008, 12, 1154–1162.

http://dx.doi.org/10.1142/S1088424608000522

25. Isago H. J. Porphyrins Phthalocyanines 2014, 18, 762–770.

http://dx.doi.org/10.1142/S1088424614500564

26. Birin K.P., Gorbunova Y.G., Tsivadze A.Y. J. Porphyrins Phthalocyanines. 2006, 10, 931–936.

http://dx.doi.org/10.1142/S1088424606000247

27. Birin K.P., Gorbunova Y.G., Tsivadze A.Y. Russ. J. Inorg. Chem. 2007, 52, 191–196.

http://dx.doi.org/10.1134/S003602360702009X

28. Nefedova I.V., Gorbunova Y.G., Sakharov S.G., Tsivadze A.Y. Russ. J. Inorg. Chem. 2005, 50, 165–173.

29. Martynov A.G., Zubareva O.V., Gorbunova Y.G., Sakharov S.G., Tsivadze A.Y. Inorganica Chim. Acta 2009, 362, 11–18.

http://dx.doi.org/10.1016/j.ica.2008.01.008

30. Stuchebryukov S.D., Selektor S.L., Silantieva D.A., Shokurov A.V. Prot. Met. Phys. Chem. Surf. 2013, 49, 189–197.

http://dx.doi.org/10.1134/S2070205113020044

31. Ishikawa N., Okubo T., Kaizu Y. Inorg. Chem. 1999, 38, 3173–3181.

http://dx.doi.org/10.1021/ic981463x

32. Magdesieva T.V., Butin K.P., Yamamoto T., Tryk D.A., Fujishima A. J. Electrochem. Soc. 2003, 150, E608–E612.

http://dx.doi.org/10.1149/1.1624297

33. Zhu P., Lu F., Pan N., Arnold D.P., Zhang S., Jiang J. Eur. J. Inorg. Chem. 2004, 3, 510–517.

http://dx.doi.org/10.1002/ejic.200300509

34. Tomilova L.G., Chernykh E.V., Nikolaeva T.B., Zelentsov V.V., Luk’yanets E.A. Zh. Obsch. Khim. (J. Gen. Chem. USSR) 1984, 54, 1678–1679 (in Russ.).

35. Rodríguez-Méndez M.L., Souto J., de Saja-González J., de Saja J.A. Sensors Actuators B Chem. 1996, 31, 51–55.

http://dx.doi.org/10.1016/0925-4005(96)80016-5

36. Gorbunova Y., Rodríguez-Méndez M.L., Kalashnikova I.P., Tomilova L.G., de Saja J.A. Langmuir 2001, 17, 5004–5010.

http://dx.doi.org/10.1021/la0102760

37. Rodríguez-Méndez M.L., Gorbunova Y., de Saja J.A. Langmuir 2002, 18, 9560–9565.

http://dx.doi.org/10.1021/la020380x

38. Bardin M., Bertounesque E., Plichon V., Simon J., Ahsen V., Bekaroglu O. J. Electroanal. Chem. Interfacial Electrochem. 1989, 271, 173–180.

http://dx.doi.org/10.1016/0022-0728(89)80073-7

39. Revina A.A., Volod’ko V.V., Radyushkina K.A. Kinetika i Kataliz 1990, 31, 1321-1327 (in Russ.).

40. Burdukov A.B., Vershinin M.A., Pervukhina N.V., Boguslvaskii E.G., Eltsov I.V., Shundrin L.A., Selector S.L., Shokurov A.V., Voloshin Y.Z. Inorg. Chem. Commun. 2014, 44, 183–187.

http://dx.doi.org/10.1016/j.inoche.2014.03.032

41. Martynov A., Biryukova V., Gorbunova Y., Tsivadze A.Y. Russ. J. Inorg. Chem. 2004, 49, 358–363.

42. Martynov A.G., Gorbunova Y.G., Khrapova I.V., Sakharov S.G., Tsivadze A.Y. Russ. J. Inorg. Chem. 2002, 47, 1479–1485.

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The Role of Oxygen in Electrochemical Reduction of Double-Decker Phthalocyaninates of Lanthanides

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