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ISSN 1998-9539

Phosphorylation of the 2,2'-Dihydroxy-1,1'-dinaphthylmethane and Synthesis of Phosphamacrocycles on its Basis

Pavel V. Slitikov,a@ and Еlena N. Rasadkinab
aBauman Moscow State Technical University, 105005 Moscow, Russian Federation
bMoscow Pedagogical State University, Institute of Biology and Chemistry, 119021 Moscow, Russian Federation
@Corresponding author E-mail:
Phosphorylation of 2,2’-dihydroxy-1,1’-dinaphthylmethane with diamidophosphites with different substituents at phosphorus atom was investigated. It was demonstrated that leaving of either two amide groups or phenyl group occurs upon formation of 1,3,2-dioxaphosphacine. Phosphamacrocyclic systems containing fragments of 2,2’-dihydroxy-1,1’-dinaphthylmethane and aromatic diols – resorcinol and 1,3-dihydroxynaphthalene – were synthesized, their low stability in solution is specified. Oxidation reactions of the synthesized compounds were studied.



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