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ISSN 1998-9539

Solid-State Synthesis, Spectroscopic and Electrochemical Properties of Symmetric A3 Type Corroles with meso-3-Chloro-4-fluorophenyl Groups and Its CoIII, MnIII and CuIII Complexes

Peng Zhang, Minzhi Li, Yu Jiang, Li Xu, Xu Liang,@1 and Weihua Zhu@2

School of Chemistry and Chemical Engineering, Jiangsu University, ZhenJiang 212013, China

@1Corresponding author E-mail: liangxuujs@126.com

@2Corresponding author E-mail: sayman@ujs.edu.cn

 

DOI: 10.6060/mhc150250z
Macroheterocycles 2015 8(1) 65-70

 

Solid-state synthesis of A3 type 5,10,15-(3-chloro-4-fluorophenyl)corrole, and its CoIII, MnIII and CuIII complexes having asymmetric meso-substituents were successfully synthesized and separated. Structural characterization by MS and 1H NMR and the spectroscopic properties by UV-vis, magnetic circular dichorism (MCD) spectra were investigated in this study. Electrochemical properties were also studied to in-depth understand the electronic structures of these corrole or metallo-corrole complexes.

 

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