Журнал "Макрогетероциклы"

^aIvanovoStateUniversity of Chemistry and Technology, 15300 Ivanovo, Russian Federation

^bG.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russian Federation

^cResearch Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russian Federation

^@Corresponding author E-mail: asvashurin@mail.ru

 

DOI: 10.6060/mhc150248v

Macroheterocycles 2015 8(4) 351-357

 

Hybrid materials based on organic polymers and Co^II tetrasulfophthalocyanines are obtained. Polymer matrix was previously activated before macrocycle anchoring. Activation was carried out by microwaves and plasma-chemical treatment of polymer surfase. The influence of polymer surface pretreatment on the degree of macrocycle anchoring is shown. It is found that pretreatment of polymer matrix by glow discharge gives better anchoring of macrocycle for the most optimal time. Catalytic activity of synthesized materials in reaction of sodium diethyldithiocarbamate mild oxidation is studied. Samples activated by microwaves and face plasma-chemical discharge have showed close catalytic activity. Simultaneously, the catalytic activity of samples activated by pretreatment of polypropylene by glow discharge at the same conditions is several times higher. Non-linear dependence of sodium diethyldithiocarbamate oxidation rate of temperature for all samples is found.