Free-Radical Reaction of Iron(II) Dichloroclathrochelate with 1,3-Dioxolane Radical Derivative: Synthesis and Structure of Macrobicyclic tris-Dioximate Bearing 1,3-Dioxolan-2-yl Ribbed Substituent

Mikhail A. Vershinin,^a Alexey B. Burdukov,^a@ Natalie V. Pervukhina,^a Ilia V. Eltsov,^b and Yan Z. Voloshin^c
^aNikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
^bNovosibirsk State University, 630090 Novosibirsk, Russia
^cNesmeyanov Institute of Organoelement Compounds RAS, 110991 Moscow, Russia
^@Corresponding author E-mail: lscc@niic.nsc.ru

DOI: 10.6060/mhc141141b
Macroheterocycles 2015 8(1) 71-74

Free-radical substitution of chlorine atom of the fluoroboron-capped iron(II) dichloroclathrochelate with 1,3-dioxolan-2-yl radical proceeds with high regioselectivity, predominantly yielding the corresponding monofunctionalized cage complex. Its molecular structure has been determined both in solution and in solid state using multinuclear NMR spectroscopy and a single-crystal X-ray diffraction experiment, respectively.

References:

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Free-Radical Reaction of Iron(II) Dichloroclathrochelate with 1,3-Dioxolane Radical Derivative: Synthesis and Structure of Macrobicyclic tris-Dioximate Bearing 1,3-Dioxolan-2-yl Ribbed Substituent

References: