Synthesis and Properties of Hexa(4-tert-butylphenoxy) Substituted [30]Trithiadodecaazahexaphyrin and its Metal Complexes

Maksim S. Filatov,^a Olga N. Trukhina,^b and Mikhail K. Islyaikin^a^@

Dedicated to Professor Oscar I. Koifman on the occasion of his 70th birthday

^aResearch Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

^bIRLoN, Universidad Autonoma de Madrid, Cantoblanco, 280409 Madrid, Spain; IMDEA Nanociencia, 28049 Madrid, Spain

^@Corresponding author E-mail: islyaikin@isuct.ru

DOI: 10.6060/mhc140504i
Macroheterocycles 2014 7(3)

A new hexa(4-tert-butylphenoxy) substituted [30]trithiadodecaazahexaphyrin was obtained by reaction of bis-5,6-(4-tert-butylphenoxy)phthalonitrile and 2,5-diamino-1,3,4-thiadiazole in ethylene glycol, as well as its NiII, Cu^II, Co^II, Zn^II 3:1 metallocomplexes were synthesized. All the compounds were characterized by UV-Vis, IR, ¹H NMR and ¹³C NMR spectroscopy, mass spectrometry and elemental analysis.

References:

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Synthesis and Properties of Hexa(4-tert-butylphenoxy) Substituted [30]Trithiadodecaazahexaphyrin and its Metal Complexes

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