Synthesis and properties of meso-arylporphyrin – closo-decaborate anion conjugates

Kseniya A. Zhdanova^a,@1, Andrey P. Zhdanov^b, Artem V. Ezhov^a, Artem N. Fakhrutdinov^a, Natal’ya A. Bragina^a, Konstantin Yu. Zhizhin^b,@2, Nikolay T. Kuznetsov^b, and Andrey F. Mironov^a

^aM.V. Lomonosov Moscow State University of Fine Chemical Technology, Moscow, 119571, Russian Federation

^bRussian Academy of Science N. S. Kournakov Institute of General and Inorganic chemistry (IGIC RAS) Moscow, 119991, Russian Federation

^@1Corresponding author E-mail: mishkina_ksyusha@mail.ru

^@2Corresponding author E-mail: zhizhin@igic.ras.ru

DOI: 10.6060/mhc140494z

Macroheterocycles 2014 7(4) 394-400

New boron-porphyrin conjugates were synthesized based on 5,10,15,20-tetrakis(4-aminophenyl)porphyrin, 5-(4- aminophenyl)-10,15,20-triphenylporphyrin, 5,10-bis(4-aminophenyl)-15,20-diphenylporphyrin and closo-decaborate anions [B₁₀H₁₀]^2-. Number of boron clusters varied from one to four. The structure of all compounds was confirmed using heteronuclear correlation methods {¹H ¹³C} HSQC and {¹H ¹³C} HMBC. Spectral properties of the conjugates were evaluated based on electron absorption spectra and steady-state fluorescence. Such complexes are novel potential donor-acceptor systems.

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Synthesis and properties of meso-arylporphyrin – closo-decaborate anion conjugates

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