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ISSN 1998-9539

New Hybrid Materials Based on the Water Soluble Zinc Phthalocyanines and V2O5·nH2O

Galina S. Zabrodina,a@ Sergey Yu. Ketkov,a Olga N. Suvorova,a Dieter Wöhrle,b Elena A. Shchupak,a Alexander I. Kirillov,a Sergey G. Makarov,a Lyubov׳ V. Kalakutskaya,a Tat׳yana I. Lopatina,a and Nadya M. Khamaletdinovaa

aG.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 603950 Nizhniy Novgorod, Russia

bUniversität Bremen, Institut für Organische und Makromolekulare Chemie, 28334 Bremen, Germany

@Corresponding author E-mail:


DOI: 10.6060/mhc140376z

Macroheterocycles 2014 7(4) 417-424


New intercalated materials based on water soluble zinc phthalocyanines and xerogel V2O5·nH2O were synthesized; the dependence of phthalocyanine:V2O5 stoichiometry ratio in the intercalate on the substituents in phthalocyanine ring was defined. According to the X-Ray diffraction data the conclusion about parallel arrangement of phthalocyanine complexes in vanadium pentoxide layers was made. (TBA)0.2V2O5·nH2O intercalate was synthesized at first time as a perspective precursor for the nanosized vanadium oxide modifications. Cationic exchange tetrabutylammonium intercalated into layered V2O5·nH2O on the water soluble phthalocyanines zinc have been show.



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