New Hybrid Materials Based on the Water Soluble Zinc Phthalocyanines and V2O5·nH2O

Galina S. Zabrodina,^a@ Sergey Yu. Ketkov,^a Olga N. Suvorova,^a Dieter Wöhrle,^b Elena A. Shchupak,^a Alexander I. Kirillov,^a Sergey G. Makarov,^a Lyubov׳ V. Kalakutskaya,^a Tat׳yana I. Lopatina,^a and Nadya M. Khamaletdinova^a

^aG.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 603950 Nizhniy Novgorod, Russia

^bUniversität Bremen, Institut für Organische und Makromolekulare Chemie, 28334 Bremen, Germany

^@Corresponding author E-mail: kudgs@mail.ru

DOI: 10.6060/mhc140376z

Macroheterocycles 2014 7(4) 417-424

New intercalated materials based on water soluble zinc phthalocyanines and xerogel V₂O₅·nH₂O were synthesized; the dependence of phthalocyanine:V₂O₅ stoichiometry ratio in the intercalate on the substituents in phthalocyanine ring was defined. According to the X-Ray diffraction data the conclusion about parallel arrangement of phthalocyanine complexes in vanadium pentoxide layers was made. (TBA)_0.2V₂O₅·nH₂O intercalate was synthesized at first time as a perspective precursor for the nanosized vanadium oxide modifications. Cationic exchange tetrabutylammonium intercalated into layered V₂O₅·nH₂O on the water soluble phthalocyanines zinc have been show.

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New Hybrid Materials Based on the Water Soluble Zinc Phthalocyanines and V2O5·nH2O

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