Structural Dynamics and Relaxation Processes with Participation of Excited Singlet and Triplet States in Sterically Hindered Porphyrins and Their Chemical Dimers

Eduard I. Zenkevich

National Technical University of Belarus, Department of Information Technologies and Robotics, 220013 Minsk, Belarus

DOI: 10.6060/mhc140597z

Macroheterocycles 2014 7(2) 103-121

It was found that meso-phenyl substitution in octaethylporphyrins led to the T₁ state shortening by ∼1000 times without considerable changes of S₁ state properties in degassed solutions at 295 K.

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Structural Dynamics and Relaxation Processes with Participation of Excited Singlet and Triplet States in Sterically Hindered Porphyrins and Their Chemical Dimers

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