Thiacalix[4]monocrowns Substituted by Sulfur-Containing Anchoring Groups: New Ligands for Gold Surface Modification

Anton A. Muravev,^a@ Svetlana E. Solovieva,^a Evgenii N. Kochetkov,^b Nina B. Mel’nikova,^b Roman A. Safiullin,^a Marsil K. Kadirov,^a Shamil K. Latypov,^a Igor S. Antipin,^a,c and Alexander I. Konovalov^c

^aA.E. Arbuzov Institute of Organic and Physical Chemistry KazSC RAS, 420088 Kazan, Russia

^bNizhny Novgorod State Medical Academy, 603005 Nizhny Novgorod, Russia

^cKazan Federal University, 420008 Kazan, Russia

^@Corresponding author E-mail: antonm@iopc.ru

DOI: 10.6060/mhc131269m

Macroheterocycles 2013 6(4) 302-307

PDF

Crown containing calix[4]arenes with thioacetate-functionalized carbon chains on lower rim in 1,3-alternate conformation which were prepared from corresponding bromo-derivatives improve adhesion between gold and biomolecules (cytochrome c and catalase).

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Thiacalix[4]monocrowns Substituted by Sulfur-Containing Anchoring Groups: New Ligands for Gold Surface Modification

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