Generation, Spectral Properties and Stability of π-Cation Radicals of (5,10,15,20-Tetraphenylporphinato)(chloro)rhodium(III)

Nataliya G. Bichan, Elena Yu. Tyulyaeva, Tatiyana N. Lomova^@

Institute of Solution Chemistry of Russian Academy of Sciences, 153045 Ivanovo, Russia

^@Corresponding author E-mail: tnl@isc-ras.ru

DOI: 10.6060/mhc121212l

Macroheterocycles 2013 6(2) 144-151

Evidence is obtained about coordination of O2 by Rh(III) porphyrins promoted by formation of H+-associate in concentrated sulfuric acid.

References

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