The First Example of Near-Infrared 4f Luminescence of Sandwich-Type Lanthanide Phthalocyaninates

Sergey S. Smola,^а Olga V. Snurnikova,^a Evgeniy N. Fadeyev,^a Anna A. Sinelshchikova,^b Yulia G. Gorbunova,^b,c Lyudmila A. Lapkina,^с Aslan Yu. Tsivadze,^b,c and Nataliya V. Rusakova^a@

^aA.V. Bogatsky Physico-Chemical Institute of National Academy of Sciences of Ukraine, 65080 Odessa, Ukraine
^bA.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences, 119071 Moscow,
Russia
^cN.S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 119991 Moscow, Russia

^@Corresponding author E-mail: lanthachem@ukr.net

Macroheterocycles 2012 5(4-5) 343-349

DOI: 10.6060/mhc2012.121193r

It was discovered that the solutions of Er^III and Yb^III sandwich double- and triple-decker complexes with tetra(15-crown-5)phthalocyanine possess 4f luminescence in near-infrared range.

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