Lanthanide Paramagnetic Probes for NMR Spectroscopic Studies of Fast Molecular Conformational Dynamics and Temperature Control. 18-Crown-6 Intramolecular Reorientation in Complexes of Cerium(III) Chelates

Sergey P. Babailov, and Anna V. Goryunova

A.V. Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia

Macroheterocycles 2012 5(2) 178-181

DOI: 10.6060/mhc2012.120469b

Using dynamic ¹Н NMR method the molecular dynamics of 18-crown-6 ether molecules in [(Ln(ptfa)₃)₂(18-
crown-6)] complexes has been studied in CDCl₃ solution.

mhc2012_t05n2_178-181.pdf (730.71 KB)

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