First Water-Soluble μ-Nitrido Dimer of Iron Phthalocyanine

Pavel A. Stuzhin,^a@ Svetlana S. Ivanova,^a Ilya Dereven’kov,^a Sergey V. Makarov,^aRadu Silaghi-Dumitrescu,^b and Heiner Homborg^c

^aDepartment of Organic Chemistry, Ivanovo State University of Chemical Technology, RF-153000 Ivanovo, Russia
^b“Babes-Bolyai” University, RO-400028 Cluj-Napoca, Romania
^cInstitute of Inorganic and General Chemistry, Christian-Albrechts-Universitat, D-24098 Kiel, Germany.

^@Corresponding author E-mail: stuzhin@isuct.ru

Macroheterocycles 2012 5(2) 175-177

DOI: 10.6060/mhc2012.120360s

μ-Nitridodimer of Fe-tetrasulfophthalocyanine μ-N(FeTSPc)₂ – perspective catalyst of redox reactions in aqueous media - was effectively prepared by two alternative routes: from the correspoding μ-oxo species μ-O(FeTSPc)₂ and by direct sulfonation of μ-N(FePc).

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