Free-radical Reaction of the Iron(II) Dichloroclathrochelate with Tetrahydrofurane Radical Derivatives: Synthesis and Structure of the Monotetrahydrofuryl-Containing Cage Complex

Mikhail A. Vershinin,^aAlexey B. Burdukov,^a@ Natalie V. Pervukhina,^a Ilia V. Eltsov,^b and Yan Z. Voloshin^c

^aNikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
^bNovosibirsk State University, 630090 Novosibirsk, Russia
^cA.N. Nesmeyanov Institute of Organoelement Compounds RAS, 110991 Moscow, Russia

^@Corresponding author E-mail: lscc@niic.nsc.ru

Macroheterocycles 2012 5(1) 11-16

DOI: 10.6060/mhc2012.120256b

Tetrahydrofuran radicals generated with diverse radical initiators efficiently substitute rib chlorine atoms in a macrobycilic iron(II) clathrochelate molecule. The reaction has the chain nature and is regioselective.

mhc2012_t05n01_11-16.pdf (920.51 KB)

References

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Журнал "Макрогетероциклы"

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