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ISSN 1998-9539

Free-radical Reaction of the Iron(II) Dichloroclathrochelate with Tetrahydrofurane Radical Derivatives: Synthesis and Structure of the Monotetrahydrofuryl-Containing Cage Complex

Mikhail A. Vershinin,a Alexey B. Burdukov,a@ Natalie V. Pervukhina,a Ilia V. Eltsov,b and Yan Z. Voloshinc


aNikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
bNovosibirsk State University, 630090 Novosibirsk, Russia
cA.N. Nesmeyanov Institute of Organoelement Compounds RAS, 110991 Moscow, Russia

@Corresponding author E-mail:


Macroheterocycles 2012 5(1) 11-16


DOI: 10.6060/mhc2012.120256b


Tetrahydrofuran radicals generated with diverse radical initiators efficiently substitute rib chlorine atoms in a macrobycilic iron(II) clathrochelate molecule. The reaction has the chain nature and is regioselective.


mhc2012_t05n01_11-16.pdf (920.51 KB)