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ISSN 1998-9539

Novel P,N-Containing Cyclophane with a Chiral Hydrophobic Cavity

Andrey A. Karasik,a@ Dmitrii V. Kulikov,a Roman M. Kuznetsov,a Anna S. Balueva,a Artur A. Akhmetgaliev,a Olga N. Kataeva,a Peter Lőnnecke,b Oleg R. Sharapov,a Yulia A. Zhelezina,a Svetlana N. Ignat’eva,a Evamarie Hey-Hawkins,b and Oleg G. Sinyashina


aA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, 420088
Kazan, Russian Federation
bInstitut für Anorganische Chemie der Universität Leipzig, 04103 Leipzig, Germany

@Corresponding author E-mail:


Macroheterocycles 2011 4(4) 324-330


DOI: 10.6060/mhc2011.4.08


Received 05.06.2011
Accepted 01.08.2011


The effective self-assembly process between phenylphosphine, formaldehyde and racemic N-alkyl-2,6-diamino-9,10-
dihydro-9,10-ethanoanthracene-11,12-dicarboximides results in the formation of novel heterocyclophanes with chiral
intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of enantioselective
molecular reactors.


Keywords: Сhiral cyclophanes, phosphines, 2,6-diaminoanthracene, covalent self-assembly.


MHC2011_t04n04_324-330.pdf (1.24 MB)




MHC2011_t04n04_324-330.pdf1.24 MB