News

Impact Factor 2017 = 1.086 has been issued by ISI Web of Knowledge (JCR 2017).

SCImago Journal & Country Rank

ISSN 1998-9539

Novel P,N-Containing Cyclophane with a Chiral Hydrophobic Cavity

Andrey A. Karasik,a@ Dmitrii V. Kulikov,a Roman M. Kuznetsov,a Anna S. Balueva,a Artur A. Akhmetgaliev,a Olga N. Kataeva,a Peter Lőnnecke,b Oleg R. Sharapov,a Yulia A. Zhelezina,a Svetlana N. Ignat’eva,a Evamarie Hey-Hawkins,b and Oleg G. Sinyashina

 

aA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, 420088
Kazan, Russian Federation
bInstitut für Anorganische Chemie der Universität Leipzig, 04103 Leipzig, Germany

@Corresponding author E-mail: karasik@iopc.ru

 

Macroheterocycles 2011 4(4) 324-330

 

DOI: 10.6060/mhc2011.4.08

 

Received 05.06.2011
Accepted 01.08.2011

 

The effective self-assembly process between phenylphosphine, formaldehyde and racemic N-alkyl-2,6-diamino-9,10-
dihydro-9,10-ethanoanthracene-11,12-dicarboximides results in the formation of novel heterocyclophanes with chiral
intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of enantioselective
molecular reactors.

 

Keywords: Сhiral cyclophanes, phosphines, 2,6-diaminoanthracene, covalent self-assembly.

 

MHC2011_t04n04_324-330.pdf (1.24 MB)

 

 

References

AttachmentSize
MHC2011_t04n04_324-330.pdf1.24 MB