Novel P,N-Containing Cyclophane with a Chiral Hydrophobic Cavity

Andrey A. Karasik,^a@ Dmitrii V. Kulikov,^a Roman M. Kuznetsov,^a Anna S. Balueva,^aArtur A. Akhmetgaliev,^a Olga N. Kataeva,^a Peter Lőnnecke,^b Oleg R. Sharapov,^aYulia A. Zhelezina,^a Svetlana N. Ignat’eva,^a Evamarie Hey-Hawkins,^band Oleg G. Sinyashin^a

^aA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, 420088
Kazan, Russian Federation
^bInstitut für Anorganische Chemie der Universität Leipzig, 04103 Leipzig, Germany

^@Corresponding author E-mail: karasik@iopc.ru

Macroheterocycles 2011 4(4) 324-330

DOI: 10.6060/mhc2011.4.08

Received 05.06.2011
Accepted 01.08.2011

The effective self-assembly process between phenylphosphine, formaldehyde and racemic N-alkyl-2,6-diamino-9,10-
dihydro-9,10-ethanoanthracene-11,12-dicarboximides results in the formation of novel heterocyclophanes with chiral
intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of enantioselective
molecular reactors.

Keywords: Сhiral cyclophanes, phosphines, 2,6-diaminoanthracene, covalent self-assembly.

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