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ISSN 1998-9539

Oxidation of Hydrocarbons with Tetrabutylammonium Oxone Catalyzed by β-Tribrominated meso-Tetraphenylporphyrinatomanganese(III) Acetate in the Presence of N-Bases

Akbar Ghaemi,a Saeed Rayati,b@ and Saeed Zakavic


aIslamic Azad University, Saveh Branch, Saveh, 39187-366 Iran

bK.N. Toosi University of Technology, Tehran, 16315-1618 Iran

cInstitute for Advanced Studies in Basic Sciences, Gava-Zang Zanjan, 45195-1159 Iran


@Corresponding author E-mail:


DOI: 10.6060/mhc2011.1.03


β-Tribrominated meso-tetraphenylporphyrinato-manganese(III) acetate (Mn(TPPBr3)OAc) as an electron-deficient metalloporphyrin shows high catalytic activity in the oxidation of less hindered conjugated double bonds and cycloalkenes by tetrabutylammonium monopersulfate.


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