Dmitry V. Belykh,a@ Irina S. Tarabukina,a Ivan V. Gruzdev,b and Alexander V. Kuchina
aInstitute of Chemistry, Komi Scientific Centre, Ural Division of Russian Academy of Sciences, 167982 Syktyvkar, Russia
bInstitute of Biology, Komi Scientific Centre, Ural Division of Russian Academy of Sciences, 167982 Syktyvkar, Russia
@Corresponding author E-mail: belykh-dv@chemi.komisc.ru, belykh-dv@mail.ru
DOI: 10.6060/mhc2010.2-3.145
It has been shown that aminomethylation of the vinyl group in Zn complexes of chlorophyll a phorbine derivatives can be accomplished under the action of bis(N,N-dimethylamino)methane in the presence of weak acid (AcOH) at room temperature. The new chlorophyll a phorbine derivatives with two N,N-dimethylaminomethyl substituents in vinyl group were synthesized.
Keywords: Methylpyropheophorbide a, methylpyropheophorbide a 13(1)-oxim, methylpyropheophorbide a 13(1)-methoxim, zinc complexes, aminomethylation, bis(N,N-dimethylamino)methane.
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