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Synthesis of Calix[4]arene Bisporphyrin on the Basis of Biladiene-a,c Dihydrobromide

Nugzar Zh. Mamardashvili@ and Oscar I. Koifman

 

Institute of Solution Chemistry of Russian Academy of Sciences, Ivanovo, 153045, Russia

 

@Corresponding author E-mail: ngm@isc-ras.ru

 

A new calix[4]arene-bisporphyrin has been synthesized following a stepwise approach. The tetrapyrrolic precursor for
bisporphyrin is 10-aryl substituted biladiene-a,c dihydrobromide. The preparation of the starting pyrrolic compounds
has been optimized with respect to the previously reported methods.

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