Pillar[5]arenes with Morpholide and Pyrrolidide Substituents: Synthesis and Complex Formation with Alkali Metal Ions

Dmitry N. Shurpik,^a Luidmila S. Yakimova,^a Leysan I. Makhmutova,^a Aigul R. Makhmutova,^a Ildar Kh. Rizvanov,^b Vitaly V. Plemenkov,^c and Ivan I. Stoikov^a@

^aKazan Federal University, A.M. Butlerov Chemical Institute, 420008 Kazan, Russian Federation

^bA.E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, 420088 Kazan, Russian Federation

^cImmanuel Kant Baltic Federal University, Institute of Biochemistry, 236041 Kaliningrad, Russian Federation

^@Corresponding author E-mail: ivan.stoikov@mail.ru

DOI: 10.6060/mhc140719s

Macroheterocycles 2014 7(4) 351-357

Novel pillar[5]arenes containing morpholide and pyrrolidide were synthesized by step-by-step functionalization of the perhydroxylated pillar[5]arene. Binding properties of the compounds toward alkali metal cations (Li⁺, Na⁺, K⁺, and Cs⁺) were investigated. The 10²-10³ M^-1 association constants were determined for the complexes obtained by derivatives of the pillar[5]arenes with alkali metal cations with 1:1 stoichiometry by electron spectroscopy. It was shown, that the Li⁺ binding was most effective.

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Pillar[5]arenes with Morpholide and Pyrrolidide Substituents: Synthesis and Complex Formation with Alkali Metal Ions

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